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Table 2 Vibrational band assignments for titanocene dichloride and the products of Group IVB metallocene dichlorides and dienestrol

From: Ability of Group IVB metallocene polyethers containing dienestrol to arrest the growth of selected cancer cell lines

Mode

Dien

Cp2TiCl2

Ti-Polymer

Zr-Polymer

Hf-polymer

OH Stretch

3415

    

CH St. Ar

3026,3005

3103

3100,3027, 3091

3100, 3027, 3005

3069, 3029, 3005

CH St. Alip

2972, 2933, 2910, 2852

 

2972, 2910, 2852

2970, 2912, 2854

2970, 2912, 2866

C = C St. Alip

1641

 

1651

1650

1650

C = C St. Ar

1603

 

1608

1604

1606

Phenylene Ske

1504

 

1500

1506

1501

(Cp) CC St

1440

 

1425

1423

1426

C-O St

1419

 

1389

1390

1425

CC Stretch

1364

 

1330

1331

1333

CH i.p. Bend

1238

 

1243

1244

1246

Ring Breathing

1166

 

1171

1171

1171

CH o.p. Bend

1093

 

1099

1099

1101

C-C St

1062

 

1040

1040

1040

CH i.p. Bend

 

1015

1012

1014

1014

CC i.p. Bend

949

 

956

952

955

CH o.p. Bend

892

 

902

900

854

CH o.p. Bend

 

820

829

827

828

CH2 Rocking

740

 

740

740

721

CC o.p. Bend

613

 

617

619

619